Try it with a proper battery. It should pair.
Sounds like the ZPower cell is not giving enough voltage to run the streaming service.
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I tested regular batteries for 5 days and everything worked fine. I found that when I put the ZPower rechargeable batteries back in, I had fewer problems, so I am wondering if they weren’t properly seate or if there could be a problem with the door. My Audi gave me a backup pair of rechargeable batteries as a precaution and I’m going to continue using the ZPower for now as I like them from an environmental POV.
For Apple Watch connectivity, you’ll have to use the Connect Clip. Apple haven’t enabled connection like the iPhone for the Apple Watch. Same for Series 4.